Solution:

7 minutes hourglass = p
11 minutes hourglass = q

Turn p and q.
P will finish at 7 minutes and then turn it again.
When q finishes (11 minutes), turn p again.
It will take 4 minutes for p to become empty.

The total time if you count is 15 minutes when p empties.

Solution:

First Person: 3 full bottles, 1 half empty bottle and 3 empty bottles.

Second Person: 3 full bottles, 1 half empty bottle and 3 empty bottles.

Third Person: 1 full bottle, 5 half empty bottles and 1 empty bottle.

Solution:

2nd

When the cylinder is spun for the first and last time, the following six outcomes are possible:

First:
First chamber is fired first. The first player loses.

Second:
Second chamber is fired first. The first player loses.

Third:
Third chamber is fired first. The first player loses.

Fourth:
Fourth chamber is fired first. The second player loses. (First shot, player 1, chamber 4 empty. Second shot player 2, chamber 5, empty. Third shot player 1, chamber 6 empty. Fourth shot player 2, chamber 1 not empty.)

Fifth:
Fifth chamber is fired first. The first player loses. (First shot, player 1, chamber 5 empty. Second shot player 2, chamber 6, empty. Third shot player 1, chamber 1 not empty.)

Sixth:
Sixth chamber is fired first. The second player loses. (First shot, player 1, chamber 6 empty. Second shot, player 2, chamber 1, not empty)

Thus, if you analyze, you will find that the second player has a 4/6 chance of winning. Therefore if you want to win the game, going second gives you better shot at it.

Solution:

89

Solution:

6

It takes two hours for one worker to paint one wall.
In six hours therefore one worker can paint 3 rooms, hence you need six painters to paint eighteen rooms

Solution:

114(37+38+39)

Solution:

Britney speaks truth on only Thursday.

Solution:

Let us rename the Five gallons basket and Three gallons basket as F and T.
Fill F completely and then pour to fill T completely. By doing this you have 2 gallons remaining in F. Pour out T entirely and then fill it with the remaining liquid from F. Now, T has 2 gallons of liquid.
Fill F fully again. Now pour the liquid to fill T which has just 1 gallons of capacity remaining. By doing this, you are left with the required 4 gallons of liquid in F.