Solution:

12

In general, with n+1 people, the number of handshakes is the sum of the first n consecutive numbers: 1+2+3+ ... + n.
Since this sum is n(n+1)/2, we need to solve the equation n(n+1)/2 = 66.
This is the quadratic equation n2+ n -132 = 0. Solving for n, we obtain 11 as the answer and deduce that there were 12 people at the party.

Since 66 is a relatively small number, you can also solve this problem with a hand calculator. Add 1 + 2 = + 3 = +... etc. until the total is 66. The last number that you entered (11) is n.

Solution:

41312432

Solution:

It can be done as shown in the picture below.

Solution:

The person on 73rd number will survive.

Explanation:
Till the number is the power of 2, the last person to survive will be the one who started it. But since the number here is not the power of 2, we will take the greatest power of 2 that is less than the number which is 64.
100 - 64 = 36
36 people are killed as 2, 4, 6, ..., 72. Thus the sword will now be given to the 73rd person. Now he is the first person to start in the remaining 64 people. Thus he will be the one to survive.

Solution:

This puzzle has no answer if you are considering this figure in a 2d domain. However if you follow it on a three-dimensional plane, you can do it like shown in the figure given.

Solution:

31

Explanation:
Ramanujan lighting the candles in binary.
11110 =30
11111 =31

Solution:

Solution is below

Solution:

Bond was suspicious of the women as one never knocks its own door at the hotel.

Solution:

I spoke with Joe.

Explanation:
There can be only two cases. Either Zoe is a liar or Joe is a liar.

First Case
Let us assume that Zoe is a liar and Joe is a truthful person.
If I asked the question from Joe, the answer will be yes. If I asked the question from Zoe, the answer will be no. Thus in this case, I must have asked from Joe.

Second Case
Let us assume that Zoe is a truthful and Joe is a liar.
If I asked the question from Joe, the answer will be yes. If I asked the question from Zoe, the answer will be no. Thus in this case as well, I must have asked from Joe only.

Solution:

9 - 8 + 76 - 5 + 4 + 3 + 21 = 100


Other ways of making number 100 (withiout using number 32)
98 + 7 + 6 - 5 - 4 - 3 + 2 - 1 = 100
98 - 7 - 6 - 5 - 4 + 3 + 21 = 100
9 - 8 + 76 - 5 + 4 + 3 + 21 = 100
98 - 7 + 6 + 5 + 4 - 3 - 2 - 1 = 100
98 + 7 - 6 + 5 - 4 + 3 - 2 - 1 = 100
98 + 7 - 6 + 5 - 4 - 3 + 2 + 1 = 100
98 - 7 + 6 + 5 - 4 + 3 - 2 + 1 = 100
98 - 7 + 6 - 5 + 4 + 3 + 2 - 1 = 100
98 + 7 - 6 - 5 + 4 + 3 - 2 + 1 = 100
98 - 7 - 6 + 5 + 4 + 3 + 2 + 1 = 100
9 + 8 + 76 + 5 + 4 - 3 + 2 - 1 = 100
9 + 8 + 76 + 5 - 4 + 3 + 2 + 1 = 100

Solution:

It has been clearly mentioned that all the boxes are labeled incorrectly. If he opens the Box3, then he will get either Dark Chocolates or Milk Chocolates as it is labeled incorrectly. Let us suppose he finds Dark Chocolates in there. Now since all are labeled incorrectly, Box B A must contain Milk Chocolates and Box B must contain Milk Chocolates and Dark Chocolates.