Solution:

4%

Explanation:
The winning chance probability is still 4% as the outcome of Samuel winning the lottery is a separate event from the 1st four losing it.

Solution:

The code word is TIE.

Let us assume that the word is MOD. Now if you are told one character of this word, you would not be able to identify the number of vowels in the word. For example if you are told M, then the word can be MOD or AIM but they both have different number of vowels. If you are told about O, then there are two words MOD and OAT which again have different number of vowels. If you are told about D, there are two words again MOD and DUE which have different numbers of vowels again.

In such manner, all the words that have M, O or D in them can be excluded. Then only word that remains is TIE.
If you are told about T, there are two words OAT and TIE which both have two vowels.
If you are told about I, there are two words AIM and TIE which both have two vowels.
If you are told about E, there are two words DUE and TIE which both have two vowels.

Thus TIE is the code word.

Solution:

Ms. Britney did it.

We will take up every person and analyze the statements over all of them one by one.

Case 1: Ms. Britney did it, then
Statement 1 => true
Statement 2 => false (as Rihanna did not do it)
Statement 3 => false (as Ms. Britney is lying)
Statement 4 => false (as Ms. Gwyneth is lying)
Our first guess itself was right but let us confirm our analysis by analyzing the statements over others.

Case 2: Ms. Rihanna did it, then
Statement 1 => false (as Ms. Britney did not do it)
Statement 2 => true
Statement 3 => true (as Ms. Britney is not lying)
As per the conditions, three statements had to be wrong but here, we have two statements right which clearly contradict the condition.

Case 3: Ms. Gwyneth did it, then
Statement 1 => false (as Ms. Britney did not do it)
Statement 2 => false (as Ms. Rihanna did not do it)
Statement 3 => false (as Ms. Britney is lying)
Statement 4 => false (as Ms. Gwyneth is lying)
She did not do it as all the statements are false.

Case 4: Ms. Yoon did it, then
Statement 1 => false (as Ms. Britney did not do it)
Statement 2 => false (as Ms. Rihanna did not do it)
Statement 3 => false (as Ms. Britney is lying)
Statement 4 => false (as Ms. Gwyneth is lying)
All four statements are false in her case as well thus she did not do it.

Therefore we have proved that Ms. Britney did it.

Solution:

Bond was suspicious of the women as one never knocks its own door at the hotel.

Solution:

Four

three placed flat on the table in a triangle(touching each other) and put the fourth one on top of them in the middle.

Solution:

The node can be connected as shown.

Solution:

You will ask, I have a number in my mind that i.e. either 2 or 3. Is the number that I have in my mind smaller or equal to the number that you are thinking of?

If Alan replies with no, he is thinking of the number 1.
If Alan replies with yes, he is thinking of the number 3.
If Alan replies with don't know, he is thinking of the number 2.

Solution:

You must put labels on the tablets as A and B before using. In that case, if you pour tablets together, you will get 3A, 2A 1B, 1A 2B or 3B. If they are from the same bottles you can take one from another bottle and save the remaining two for another day. If you get two from same and one from other, you can draw one from another bottle and you will have two pairs of which you can eat one and save the other.

Solution:

Birbal drew another line that was larger than the pre-drawn line. Now the pre drawn line was smaller.

Solution:

2 people

Say 2 helpers are Helper1 & Helper2

Helper1 food Helper2 food McDuck's Food
End of Day 1 : 1 4 4
Now 'A' will head back

End of Day 2 : N/A 2 4
Now 'B' will head back

Now Mr. McDuck have 4 day food :-)

Solution:

If you see the picture, they formed a pentagonal shape and achieved the required.