Solution:

The code word is TIE.

Let us assume that the word is MOD. Now if you are told one character of this word, you would not be able to identify the number of vowels in the word. For example if you are told M, then the word can be MOD or AIM but they both have different number of vowels. If you are told about O, then there are two words MOD and OAT which again have different number of vowels. If you are told about D, there are two words again MOD and DUE which have different numbers of vowels again.

In such manner, all the words that have M, O or D in them can be excluded. Then only word that remains is TIE.
If you are told about T, there are two words OAT and TIE which both have two vowels.
If you are told about I, there are two words AIM and TIE which both have two vowels.
If you are told about E, there are two words DUE and TIE which both have two vowels.

Thus TIE is the code word.

Solution:

Tilt the barrel until the fruit juice barely touches the lip of the barrel. If the bottom of the barrel is visible then it is less than half full.If the barrel bottom is still completely covered by the fruit juice, then it is more than half full.

Solution:

He should shoot at the ground.

If Kangwa shoots the ground, it is Rafael's turn. Rafael would rather shoot at Ferdinand than Kangwa, because he is better.
If Rafael kills Ferdinand, it is just Kangwa and Rafael left, giving Kangwa a fair chance of winning.
If Rafael does not kill Ferdinand, it is Ferdinand's turn. He would rather shoot at Rafael and will definitely kill him. Even though it is now Kangwa against Ferdinand, Kangwa has a better chance of winning than before.

Solution:

Selfie
Explanation:
: Selfie = is six letter word
: Self = The first four letter is me.
: e = The second and last letter are the same.
: fee = The fourth second and last letter are payment.

Solution:

You will ask, I have a number in my mind that i.e. either 2 or 3. Is the number that I have in my mind smaller or equal to the number that you are thinking of?

If Alan replies with no, he is thinking of the number 1.
If Alan replies with yes, he is thinking of the number 3.
If Alan replies with don't know, he is thinking of the number 2.

Solution:

7

Explanation:
8th is bald man head, check the video below.

Solution:

Read the question carefully again. New Year do falls after Christmas but that happens if two different years. The question is put up against the year 2050 and thus there will be 51 weeks and 2 days in between them as New Year will appear on 1 January 2050 and Christmas will happen on 25 December 2050.

Solution:

73

Explanation:
It's a very famous puzzle known as "Josephus Problem Puzzle". It can be solved in various ways but the trick to solve this problem is illustrated below.

Binay number of 100 is: 1100100
complement pf 100 is 0011011, whose decimal equivalent is 27.
The desired answer will be 100 - 27 = 73

Solution:

Adam and Eve were the only people without navel. As they were not born out of a mother, they never had umbilical cords and thus never had navels.

Solution:

The best thing for you will be to shoot your first shot in air.

If you try to shoot at Jack and hits him by chance, Leo always hits on the target and you are dead.

If you choose to shoot at Leo and hits him by chance, then there is a fifty percent chance that Jack will hit you.

If you shoot in air, the next turn is of Jack and he knows that Leo is a better shooter which means that he will shoot at him. If he misses, he is definitely dead as Leo will shoot on him coz he shot at him. The next turn will be yours and you stand a 1/3rd chance of hitting him. Also if, he is able to hit Leo. The next chance is yours again and you can try the 1/3rd probability of hitting over Jack.

This is the best situation that you can face. At every other possible way, you will face a worse situation for sure.

Solution:

The attached picture shows you how you can do it. If you were able to deduce any other way, feel free to comment.