Solution:

19

Explanation:
The children can purchase 19 chocolates in return.

Out of 77 wrappers, 75 will be used to buy 15 chocolates and two will be left spare.
The 15 chocolates will create 15 empty wrappers that can be exchanged to get three chocolates.
Three chocolates will return three wrappers which will help them buy another chocolate.
Now the wrapper from this chocolate and the two spare that were left earlier will get them another chocolate.
15 + 3 + 1 = 19

Solution:

Both will rotate at Same speed.

Explanation:
Gears of the same size will always rotate at constant speeds despite any smaller or larger gears in between them.

Solution:

The first step that they will take will be a leap of logic. What it means is that they will deduce that every color must appear twice at least. Why? Because the master logician has assured them that the puzzle will not be impossible for anyone of them. And if a color appears only once in the circle, the person wearing it will have no clue about that color which will not be fair for him.

Then the logicians will follow the same and look for all the colors of hats in the circle. If one of them sees a color just once, he can safely assume that he is also wearing the hat of the same color as by leap of logic, no color can appear just once. Thus when the bell is rung, he will leave.

In the similar fashion, if anyone sees another color just once, he can determine that he is wearing the hat of the same color and will leave when the bell rings or will be disqualified and sent home. Unvaryingly, if a color is seen twice, they will be eliminated after the first bell. Hence, there must be at least three hats of any of the remaining color.

Assume that you are sitting in the circle and you don’t see a color once but see it twice. Then if they were the only two hats of the same color, the logicians must have left at the first bell already. But they did not. Which means that there are three hats of that color and you are wearing one. Thus you will leave after the second bell.

Solution:

Anybody will prefer the shop in the eastern market for sure. There are two reasons for it:
Firstly, since there are only two barbers in the town, the one running the shop in eastern market must have gotten his hair done by the one running the shop in the northern market and vice versa. Thus, if the barber in the eastern market has a shabby haircut, it must be due to the incompatibility.
Secondly, the neat and clean shop can be due to the scarcity of customers as well. While the untidy place refers to the fact that so many customers get their hair done in that shop.

Thus any one will opt for the barber shop in the eastern market.

Solution:

Hhe hung herself using big Ice slabs , which are now now melted and hence puddle of water.

Solution:

At every floor, the detective had to open the window himself. If the man had committed suicide, then at least one of the windows must have been open. A person who is committing suicide won’t close the window behind him. Thus he knows that someone pushed him off the edge and closed the window afterwards.

Solution:

12 steps:

Steps 11 Liter jug 6 Liter Jug
1. 11 -
2. 5 6
3. 5 0
4. 0 5
5. 11 5
6. 10 6
7. 10 0
8. 4 6
9. 4 0
10. 0 4
11. 11 4
12. 9 6 ==> i found 9 liter in 11liter jug(as required)

Solution:

There is a simple logic to solve this question.
The size of the chocolate is 2 x 8. Thus, you need to have 2 x 8 = 16 pieces.
Every time you break the chocolate, you will get one extra piece.
Thus, to get 16 pieces, you must break it (16 - 1) = 15 times.

Solution:

45 minutes

Explanation :
All you have to do is burn the first rope from both the ends and the second rope from one end only simultaneously. The first rope will burn in 30 minutes (half of an hour since we burned from both sides) while the other rope would have burnt half. At this moment, light the second rope from the other end as well. Where, the second rope would have taken half an hour more to burn completely, it will take just 15 minutes as we have lit it from the other end too.

Thus you have successfully calculated 30+15 = 45 minutes with the help of the two given ropes.

Solution:

See the figure for the answer. Wasn't it a bit tricky?

Solution:

The attached picture gives away the solution. If you can find another solution, do send us yours.