Solution:

In the picture you can find the green matchsticks. We have moved them from the bottom and placed them in the middle. It was a bit tricky but now you have your desired result.

Solution:

The guard and the prisoner cross the river
The guard comes back
The guard and the girl cross the river.
The guard and the prisoner comes back.
The mother and the girl cross the river.
Mother comes back
The mother and the father cross the river
Father comes back
The guard and the prisoner cross the river
Mother comes back
The father and the mother cross the river
Father comes back
The father and the boy cross the river
The guard and the prisoner comes back
The guard and the boy cross the river
The guard comes back
The guard and the prisoner cross the river.

Solution:

Sam : 2
Dean : 5
Castiel : 7

Age diff
7 - 2 = '5' is prime
7 - 5 = '2' is prime
5 - 2 = '3' is prime

Solution:

28 =>1+2+4+7+14

cannot be 1 (as number cannot be included)

Solution:

prinka is 10, in a system that awards five for each vowel.

Solution:

20
Just count the nines in the numbers: 6, 16, 26, 36, 46, 56, 76, 86, 96, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69.
Note: 66 contains TWO nines

Solution:

A) Fill 5 ml gallon ( 5mlGallon - 5, 3mlGallon - 0)
B) Transfer to 3 ml gallon (5mlGallon - 2, 3mlGallon - 3)
C) Empty 3 ml gallon ( 5mlGallon - 2, 3mlGallon - 0)
D) Transfer 2 ml from 5 ml gallon to 3 ml gallon (5mlGallon - 0, 3mlGallon - 2)
E) Fill 5 ml gallon(5mlGallon - 5, 3mlGallon - 2)
F) Transfer 1 ml from 5 ml gallon to 3 ml gallons(5mlGallon - 4, 3mlGallon - 3)

Solution:

2 people

Say 2 helpers are Helper1 & Helper2

Helper1 food Helper2 food McDuck's Food
End of Day 1 : 1 4 4
Now 'A' will head back

End of Day 2 : N/A 2 4
Now 'B' will head back

Now Mr. McDuck have 4 day food :-)

Solution:

You must put labels on the tablets as A and B before using. In that case, if you pour tablets together, you will get 3A, 2A 1B, 1A 2B or 3B. If they are from the same bottles you can take one from another bottle and save the remaining two for another day. If you get two from same and one from other, you can draw one from another bottle and you will have two pairs of which you can eat one and save the other.

Solution:

13 numbers

Explanation:
Since we are looking to find odd reminder which implies that the remainder will be either 1 or 3
Therefore number must follow below two conditions:
A) We can list number 5n + 1 or 5n + 3. (where n = 0,1,2,3.....)
B) The number must end in 1 or 3.

List of such numbers less than 100 are:
1, 3, 11, 13, 21, 23, 31, 33, 41, 43, 51, 53, 61, 63, 71, 73, 81, 83, 91, 93

Let's remove the nonprime ones which are 1, 21, 33, 51, 63, 81 and 91

So, I will be left with 13 numbers which fit the bill.
3, 11, 13, 23, 31, 41, 43, 53, 61, 71, 73, 83 and 93

Solution:

The attached picture gives away the solution. If you can find another solution, do send us yours.