Solution:

He can choose to die of old age

Solution:

Firstly: Policeman should take the thug across the river thames and escort the boat back with him. (Thug across, everyone else on this side)
Then, Policeman will take one cat along, leave it there, and on the way back, bring back the thug (since thug cannot be left with anyone without policeman's supervision).
Then Mrs. Mother will take the second cat on the other side. Drop it there and bring the boat back. For the 4th trip, Mrs. Mother And Mr. Father Will travel to the other side, and Mrs. Mother will stay there, and MR. Father will bring the boat back. (Now Mrs. Mother and 2 cats are on the other side.)
5th trip, the policeman takes the thug across. Both of them stay there and Mrs. Mother will come back. Then for the next trip, Mr. Father and Mrs. Mother will go on the boat, and Mrs. Mother will stay there, and Mr. Father will return back.
Then for the 7th trip, Mr. Father will travel with one dog. On the return, the policeman and the thug will return. Then in the next trip, the Policeman will take the second dog. (Now Mrs. Mother and her two cats; Mr. Father and his two dogs and the Policeman is here).
Now finally the policeman takes the boat on the other side and brings back the thug.
Tough one, right ?

Solution:

We now have a square of 3x3 size, 2 squares of 2x2 size and 5 squares of 1x1 size.

Solution:

2, 3, 10 and 10
To maintain the difference of eight and keeping in mind the third and fourth hint, the first and third cards can be 2 and 10 or 10 and 2. But keeping in mind the first hint, we know that the first card is 2 and the third is 10. Similarly, if we see the fifth hint, the difference between the second and fourth card should be 7. Thus we know that the second card is 3 and the fourth card is 10.

Solution:

One of the cop will move clockwise while the other will move anti-clockwise every day. In such a manner, they will catch the thief in minimum seven days.

Solution:

1653

Explanation:
For an ideal case, the batsman will hit a six on each ball. But if he hits six on the last ball of the over, the strike will change in the next over. Thus, the best he can do in the last ball is run 3 runs so that he retains the strike even in the next over. Thus the total runs that he can score in each over:
6 * 5 + 3 = 33
But this will have to go like it only till the 49th over. In the last over, he can hit a six in the last ball as well as that will be the last ball of the match.
Thus runs for the last over will be 6 * 6 = 36.
Hence the maximum runs = 33 * 49 + 36 = 1653

Solution:

5 leopard and one sheep

since all animal are rational , once 1st leopard eats the sheep all the rest of leopard would know about this.

Solution:

3 1 2 2 1 1
1 3 1 1 2 2 2 1

Read Line as one 1 => 1
Read Line 2 as two one => 2 1
Read Line 3 as one two and one one => 1 2 1 1
and so on.

Solution:

The man asked the king that he wanted to die of old age.

Solution:

Blue could only be wearing white or red and we know that there is already someone else wearing the white shirt so Mr. Blue could only be wearing the red shirt.

Mr. White could have only been wearing a blue or a red shirt, and red is already taken, so Mr. White is wearing a blue shirt.

Mr. Red now has to be wearing a white shirt.

Solution:

73

Explanation:
It's a very famous puzzle known as "Josephus Problem Puzzle". It can be solved in various ways but the trick to solve this problem is illustrated below.

Binay number of 100 is: 1100100
complement pf 100 is 0011011, whose decimal equivalent is 27.
The desired answer will be 100 - 27 = 73