Solution:

Let us rename the Five gallons basket and Three gallons basket as F and T.
Fill F completely and then pour to fill T completely. By doing this you have 2 gallons remaining in F. Pour out T entirely and then fill it with the remaining liquid from F. Now, T has 2 gallons of liquid.
Fill F fully again. Now pour the liquid to fill T which has just 1 gallons of capacity remaining. By doing this, you are left with the required 4 gallons of liquid in F.

Solution:

A cigar stuck in the wall

Solution:

Now there can be two solutions to the given situation because there can be two situations:
Suppose if B and C have same colors, A will know that his color is the other one and he will be able to speak up the first.
Now if B and C do not have same colors, A will stay silent. This will tell B that his and C's colors are different. Thus he will speak up first.

So either A or B will speak up first depending on the situation.

Solution:

Four

three placed flat on the table in a triangle(touching each other) and put the fourth one on top of them in the middle.

Solution:

It can be done in 8 moves as shown in the animated image below.

Solution:

10

Explanation:
Equation 1 + 9 + 11 = 1 can be derived from
One (o) + nine (n) + eleven (e) = one => 1

Similarly for equation,
12 + 11 + 9
Twelve (t) + eleven (e) + nine (n) => ten (10)

Solution:

13 + 11 + 6 = 30

Explanation
The trick is that you just need to rotate '9' to form '6'.

Solution:

Just 2

Day One: You make your first cut at the 1/7th mark and give that to the worker.
Day Two: You cut 2/7ths and pay that to the worker and receive the original 1/7th in change.
Day three: You give the worker the 1/7th you received as change on the previous day.
Day four: You give the worker 4/7ths and he returns his 1/7th cut and his 2/7th cut as change.
Day Five: You give the worker back the 1/7th cut of gold.
Day Six: You give the worker the 2/7th cut and receive the 1/7th cut back in change.
Day Seven: You pay the worker his final 1/7th.

Solution:

1/3

Explanation
Assuming T1 is the Toy for brother1, T2 is the toy for brother2 and T3 is the toy for brother3.

Following are the possible cases for toys distribution:

Boy1 Boy2 Boy3
T1 T2 T3
T1 T3 T2
T2 T1 T3
T2 T3 T1 .... (A)
T3 T1 T2 .... (B)
T3 T2 T1

In both steps (A) & (B), no one gets the correct toy.
Therefore probability that none brother can get the own toy is 2/6 = 1/3

Solution:

From top to bottom, the flavors are :

nutty-chocolate
peppermint
orange
Jamaica
walnut

Solution:

73

Explanation:
It's a very famous puzzle known as "Josephus Problem Puzzle". It can be solved in various ways but the trick to solve this problem is illustrated below.

Binay number of 100 is: 1100100
complement pf 100 is 0011011, whose decimal equivalent is 27.
The desired answer will be 100 - 27 = 73