Solution:

Pick 1st.

Explanation:
> Take 1 coin
> Pick the opposite number of coins from the other soldier i.e if other soldier pick 1 coin, you pick 2 and if he picks 2 coins you pick one
> After 15 moves, coins remaining will be 23 - 1 - 7(2+1) = 1
> The other solider need to pick the last and he will loose.

Solution:

XIX is the answer which refers to nineteen in roman numeric system. On taking out one i.e. I, we will get XX that is equal to twenty.

Solution:

Slumdog Millionare = Slum + Dog + Million + air

Solution:

73

Explanation:
It's a very famous puzzle known as "Josephus Problem Puzzle". It can be solved in various ways but the trick to solve this problem is illustrated below.

Binay number of 100 is: 1100100
complement pf 100 is 0011011, whose decimal equivalent is 27.
The desired answer will be 100 - 27 = 73

Solution:

Read the question carefully again. New Year do falls after Christmas but that happens if two different years. The question is put up against the year 2050 and thus there will be 51 weeks and 2 days in between them as New Year will appear on 1 January 2050 and Christmas will happen on 25 December 2050.

Solution:

See the figure for the answer. Wasn't it a bit tricky?

Solution:

Sam : 2
Dean : 5
Castiel : 7

Age diff
7 - 2 = '5' is prime
7 - 5 = '2' is prime
5 - 2 = '3' is prime

Solution:

Put one black rock in one sack and put all the rest in the other one. In such manner you will get about 3/4 probability of surviving.

Solution:

2, 3, 10 and 10
To maintain the difference of eight and keeping in mind the third and fourth hint, the first and third cards can be 2 and 10 or 10 and 2. But keeping in mind the first hint, we know that the first card is 2 and the third is 10. Similarly, if we see the fifth hint, the difference between the second and fourth card should be 7. Thus we know that the second card is 3 and the fourth card is 10.

Solution:

one fish, one cat and one dog.

Explanation:
The question might appear a bit difficult in the starting but if you analyze the statements, you will realize that it is just a tricky one.

All except two were fishes and all except two were cats. With these statements we can assume that two of the animals were not fishes and two were not cats. Now one of those animals that are not fishes can be a cat and one of those two animals that are not cats can be a fish. Just carry out the same analysis for the statement that all except two animals were not dogs and you will come across the result i.e.:
In that competition, there was one fish, one cat and one dog.

Solution:

Daughter.