Solution:

2nd

When the cylinder is spun for the first and last time, the following six outcomes are possible:

First:
First chamber is fired first. The first player loses.

Second:
Second chamber is fired first. The first player loses.

Third:
Third chamber is fired first. The first player loses.

Fourth:
Fourth chamber is fired first. The second player loses. (First shot, player 1, chamber 4 empty. Second shot player 2, chamber 5, empty. Third shot player 1, chamber 6 empty. Fourth shot player 2, chamber 1 not empty.)

Fifth:
Fifth chamber is fired first. The first player loses. (First shot, player 1, chamber 5 empty. Second shot player 2, chamber 6, empty. Third shot player 1, chamber 1 not empty.)

Sixth:
Sixth chamber is fired first. The second player loses. (First shot, player 1, chamber 6 empty. Second shot, player 2, chamber 1, not empty)

Thus, if you analyze, you will find that the second player has a 4/6 chance of winning. Therefore if you want to win the game, going second gives you better shot at it.

Solution:

60 minutes

Explanation:
Roy will be able to consume all the five tablets in an hour.

Tablet 1 will be taken in 0 min.
Tablet 2 will be taken in 15 min.
Tablet 3 will be taken in 30 min.
Tablet 4 will be taken in 45 min.
Tablet 5 will be taken in 60 min.

Solution:

888 + 88 + 8 + 8 + 8 = 1000

Solution:

In the corners of the square, tighten two ropes. Tighten another rope between them by putting rings on each rope. That rope should be tightened on the sheep's neck on the other end.

Solution:

2 people

Say 2 helpers are Helper1 & Helper2

Helper1 food Helper2 food McDuck's Food
End of Day 1 : 1 4 4
Now 'A' will head back

End of Day 2 : N/A 2 4
Now 'B' will head back

Now Mr. McDuck have 4 day food :-)

Solution:

28 =>1+2+4+7+14

cannot be 1 (as number cannot be included)

Solution:

A Spider

Solution:

9 - 8 + 76 - 5 + 4 + 3 + 21 = 100


Other ways of making number 100 (withiout using number 32)
98 + 7 + 6 - 5 - 4 - 3 + 2 - 1 = 100
98 - 7 - 6 - 5 - 4 + 3 + 21 = 100
9 - 8 + 76 - 5 + 4 + 3 + 21 = 100
98 - 7 + 6 + 5 + 4 - 3 - 2 - 1 = 100
98 + 7 - 6 + 5 - 4 + 3 - 2 - 1 = 100
98 + 7 - 6 + 5 - 4 - 3 + 2 + 1 = 100
98 - 7 + 6 + 5 - 4 + 3 - 2 + 1 = 100
98 - 7 + 6 - 5 + 4 + 3 + 2 - 1 = 100
98 + 7 - 6 - 5 + 4 + 3 - 2 + 1 = 100
98 - 7 - 6 + 5 + 4 + 3 + 2 + 1 = 100
9 + 8 + 76 + 5 + 4 - 3 + 2 - 1 = 100
9 + 8 + 76 + 5 - 4 + 3 + 2 + 1 = 100

Solution:

If the man killed himself, he would not have been able to rewind the cassette. Thus it is clear someone else killed him.

Solution:

In the picture you can find the green matchsticks. We have moved them from the bottom and placed them in the middle. It was a bit tricky but now you have your desired result.

Solution:

'five'

Its the count of alphabet