Solution:

2nd

When the cylinder is spun for the first and last time, the following six outcomes are possible:

First:
First chamber is fired first. The first player loses.

Second:
Second chamber is fired first. The first player loses.

Third:
Third chamber is fired first. The first player loses.

Fourth:
Fourth chamber is fired first. The second player loses. (First shot, player 1, chamber 4 empty. Second shot player 2, chamber 5, empty. Third shot player 1, chamber 6 empty. Fourth shot player 2, chamber 1 not empty.)

Fifth:
Fifth chamber is fired first. The first player loses. (First shot, player 1, chamber 5 empty. Second shot player 2, chamber 6, empty. Third shot player 1, chamber 1 not empty.)

Sixth:
Sixth chamber is fired first. The second player loses. (First shot, player 1, chamber 6 empty. Second shot, player 2, chamber 1, not empty)

Thus, if you analyze, you will find that the second player has a 4/6 chance of winning. Therefore if you want to win the game, going second gives you better shot at it.

Solution:

This can be done if you draw a five pointed star and place the balls on the corners and intersection points. See the figure to understand better.

Solution:

The stranger said that he thought the room was his. If so, he must have had the keys to the room and thus he must not have knocked.

Solution:

The Bangladeshi seaman is the thief. This is because the Japanese flag cannot be identified as upside down as it is the same both ways. Thus he is just trying to escape the situation.

Solution:

A) Fill 5 ml gallon ( 5mlGallon - 5, 3mlGallon - 0)
B) Transfer to 3 ml gallon (5mlGallon - 2, 3mlGallon - 3)
C) Empty 3 ml gallon ( 5mlGallon - 2, 3mlGallon - 0)
D) Transfer 2 ml from 5 ml gallon to 3 ml gallon (5mlGallon - 0, 3mlGallon - 2)
E) Fill 5 ml gallon(5mlGallon - 5, 3mlGallon - 2)
F) Transfer 1 ml from 5 ml gallon to 3 ml gallons(5mlGallon - 4, 3mlGallon - 3)

Solution:

If you see the picture, they formed a pentagonal shape and achieved the required.

Solution:

2 cakes

At each toll bridge you are required to give half of your cakes, and you receive one back. Which leaves you with 2 cakes after every bridge.

Solution:

This puzzle has no answer if you are considering this figure in a 2d domain. However if you follow it on a three-dimensional plane, you can do it like shown in the figure given.

Solution:

The code word is TIE.

Let us assume that the word is MOD. Now if you are told one character of this word, you would not be able to identify the number of vowels in the word. For example if you are told M, then the word can be MOD or AIM but they both have different number of vowels. If you are told about O, then there are two words MOD and OAT which again have different number of vowels. If you are told about D, there are two words again MOD and DUE which have different numbers of vowels again.

In such manner, all the words that have M, O or D in them can be excluded. Then only word that remains is TIE.
If you are told about T, there are two words OAT and TIE which both have two vowels.
If you are told about I, there are two words AIM and TIE which both have two vowels.
If you are told about E, there are two words DUE and TIE which both have two vowels.

Thus TIE is the code word.

Solution:

The numbers that have been written over the calendar are:
12, 4, 8 and 3

A few numbers have been circled under particular months. The curious thing is that the numbers that have been written are the same number of corresponding months under which the dates have been marked.

What we can judge by the overall calendar is that the dates that have been marked may refer to the letters at that position in the month's name. In addition, the written numbers can be the position of those letters. Let's simplify below:

12th month is December
The number marked under December = 5
The fifth letter of December = M

4th month is April
The number marked under April = 4
The fourth letter of April = I

8th month is August
The number marked under August is 6
The sixth letter of August = T

3rd month is March
The numbers marked under March are 4 and 5
The fourth and fifth letter of March = C and H

When you combine the letters, you get the name as MITCH.
Therefore, Mitch is the killer.

Solution:

Solution can be verified from the picture below.