Solution:

The conversation taking place in DST when there is a gap of approx 1hour in one of the city.

Explanation:
Daylight Saving Time (DST) is the practice of setting the clocks forward 1 hour from the standard time during the summer months, and back again in the fall, in order to make better use of natural daylight.
Therefore in case of DST, one city has time 1:30 and another city also can have time 1:30 as in one of them DST has applied and in other it's not.

Solution:

She is near the trunk of the tree as shown below.

Solution:

I am Spice

Explanation:
Spice is hot if you remove first two alphabets then it will become "ice", which is really cold.

Solution:

The mules is moving in circular path and hence outside legs travels more distance than inner legs.

Solution:

Upon reaching each room, he found out that the window facing the dead body was closed. He had to open the window himself. This tells that there was somebody else with him who closed the window. If he would have committed suicide, at least one window would have been open.

Solution:

He should shoot at the ground.

If Kangwa shoots the ground, it is Rafael's turn. Rafael would rather shoot at Ferdinand than Kangwa, because he is better.
If Rafael kills Ferdinand, it is just Kangwa and Rafael left, giving Kangwa a fair chance of winning.
If Rafael does not kill Ferdinand, it is Ferdinand's turn. He would rather shoot at Rafael and will definitely kill him. Even though it is now Kangwa against Ferdinand, Kangwa has a better chance of winning than before.

Solution:

Move and then pour all juice from second glass to fifth glass.

Solution:

Fifteen minutes can easily be measure using these two hour glasses.

Step 1: He will start both the hourglass.

Step 2: The moment the eleven minute hourglass is empty, he will invert it.

Step 3: When the thirteen minutes hourglass is empty, he will invert the eleven minute hourglass.
In step 3, we will have counted thirteen minutes. Since we inverted the eleven minute hourglass in step 2, it started from fresh and was inverted just for two minutes (13-11=2). In this manner when it is reversed when the thirteen minute hourglass is finished, it will have two minutes of sand left. This time when the sand finishes, he will have measured fifteen minutes. (13+2=15)

Solution:

Bond was suspicious of the women as one never knocks its own door at the hotel.

Solution:

45 minutes

Explanation :
All you have to do is burn the first rope from both the ends and the second rope from one end only simultaneously. The first rope will burn in 30 minutes (half of an hour since we burned from both sides) while the other rope would have burnt half. At this moment, light the second rope from the other end as well. Where, the second rope would have taken half an hour more to burn completely, it will take just 15 minutes as we have lit it from the other end too.

Thus you have successfully calculated 30+15 = 45 minutes with the help of the two given ropes.

Solution:

I spoke with Joe.

Explanation:
There can be only two cases. Either Zoe is a liar or Joe is a liar.

First Case
Let us assume that Zoe is a liar and Joe is a truthful person.
If I asked the question from Joe, the answer will be yes. If I asked the question from Zoe, the answer will be no. Thus in this case, I must have asked from Joe.

Second Case
Let us assume that Zoe is a truthful and Joe is a liar.
If I asked the question from Joe, the answer will be yes. If I asked the question from Zoe, the answer will be no. Thus in this case as well, I must have asked from Joe only.