Solution:

Fifteen Minutes.

After frying for five minutes, you can take out one steak and put the third one inside while turning the other one inside. After five more minutes, one steak is fried from both sides and you can take it out. Now put in the steak that we removed and turn the other one inside. After five more minutes, they both will also be fried from both sides.

Solution:

74658

* 8 + 6 =14
* 5 - 4 = 1
* 7 = 2*4 - 1
* 4 + 6 = 10
* 7+4+6+5+8 = 30

Solution:

192

Explanation:
I started with the number 192.
Adding the reversed 291 to 192 gave me 483.
Similarly,
483 + 384 = 867
867 + 768 = 1635
1635 + 5361 = 6996

Solution:

Sam : 2
Dean : 5
Castiel : 7

Age diff
7 - 2 = '5' is prime
7 - 5 = '2' is prime
5 - 2 = '3' is prime

Solution:

You can ask this question to any one person, "if I ask the man who is next you: which is the correct way and the road to the village, what would the person next to you answer?"
If you happened to ask this question to the liar, he will show you the wrong way.
And if you happened to ask this question to the one who says truth, he will also show you the wrong way.
Once you are done with this, take the other way. This will lead you to the village

Solution:

We now have a square of 3x3 size, 2 squares of 2x2 size and 5 squares of 1x1 size.

Solution:

2100 miles.

Each vowel equivalent to 500 and each consonant equivalent to -200

Solution:

Fred Odea won.

Just look at the announcement lines. The first sentence in 'Ok now everybody!' If you take out just the first letter of every word, it will form 'ONE'. In the same manner the second sentence 'The winner of…..' will give form 'TWO' and the third sentence 'The Hardest Riddle Ever Event.' Will form THREE.

Thus the final sentence must form FOUR. There is only one candidate who can suffice with the first two letter and he is Fred Odea. The final sentence of the mastermind must be, 'Fred Odea: Ultimate Riddler!'

Solution:

The person on 73rd number will survive.

Explanation:
Till the number is the power of 2, the last person to survive will be the one who started it. But since the number here is not the power of 2, we will take the greatest power of 2 that is less than the number which is 64.
100 - 64 = 36
36 people are killed as 2, 4, 6, ..., 72. Thus the sword will now be given to the 73rd person. Now he is the first person to start in the remaining 64 people. Thus he will be the one to survive.

Solution:

Blue could only be wearing white or red and we know that there is already someone else wearing the white shirt so Mr. Blue could only be wearing the red shirt.

Mr. White could have only been wearing a blue or a red shirt, and red is already taken, so Mr. White is wearing a blue shirt.

Mr. Red now has to be wearing a white shirt.

Solution:

Since each one of them gave one answer wrong, this means that each one of them gave two answers right.

Let us assume that Student A gave a wrong answer to the first question. This will mean that Student B also gave a wrong answer for the first. This will conclude that the rest of the two answers given by them are correct. However, the answers are different and thus it is not possible.

Thus both Student A and Student B must be right with the first question and the answer to the first is two.

If you keep applying the same logic, you will come to a conclusion that following are the correct answers:
Q1. Two
Q2. Three
Q3. Two