Solution:

192

Explanation:
I started with the number 192.
Adding the reversed 291 to 192 gave me 483.
Similarly,
483 + 384 = 867
867 + 768 = 1635
1635 + 5361 = 6996

Solution:

2 minutes (duration between 9:59 and 10:01)

Solution:

Sam : 2
Dean : 5
Castiel : 7

Age diff
7 - 2 = '5' is prime
7 - 5 = '2' is prime
5 - 2 = '3' is prime

Solution:

Never

Explanation:
In the question, the distance of x miles is given at a particular moment. The middle car is running at that time at 50 MPH. The distance will keep increasing with time as three are running at different speeds. It will increase by x miles every hour till a certain point of time and then it will start decreasing till the fastest car meets the slowest again.

As per question, all the cars stop then. Thus, the distance will never be x miles again.

Solution:

It can be done as shown in the picture below.

Solution:

Fred Odea won.

Just look at the announcement lines. The first sentence in 'Ok now everybody!' If you take out just the first letter of every word, it will form 'ONE'. In the same manner the second sentence 'The winner of…..' will give form 'TWO' and the third sentence 'The Hardest Riddle Ever Event.' Will form THREE.

Thus the final sentence must form FOUR. There is only one candidate who can suffice with the first two letter and he is Fred Odea. The final sentence of the mastermind must be, 'Fred Odea: Ultimate Riddler!'

Solution:

If you ask the guard who always tells the truth, he would tell you the other guard would point you to the door of death. If you ask the guard who always lies, he would tell you the opposite door of the truth-telling guard and point you to the door of death. In either case, both guards will point to the door of death so you should choose the other one.

Solution:

They are matched as shown in the picture below.

Solution:

2, 3, 10 and 10
To maintain the difference of eight and keeping in mind the third and fourth hint, the first and third cards can be 2 and 10 or 10 and 2. But keeping in mind the first hint, we know that the first card is 2 and the third is 10. Similarly, if we see the fifth hint, the difference between the second and fourth card should be 7. Thus we know that the second card is 3 and the fourth card is 10.

Solution:

You must put labels on the tablets as A and B before using. In that case, if you pour tablets together, you will get 3A, 2A 1B, 1A 2B or 3B. If they are from the same bottles you can take one from another bottle and save the remaining two for another day. If you get two from same and one from other, you can draw one from another bottle and you will have two pairs of which you can eat one and save the other.

Solution:

This can be done if you draw a five pointed star and place the balls on the corners and intersection points. See the figure to understand better.