Solution:

12 Angry Men

Explanation:
12 (dozen = 12)
Angry (Angry Bed)
Men

Solution:

Four

three placed flat on the table in a triangle(touching each other) and put the fourth one on top of them in the middle.

Solution:

9 - 8 + 76 - 5 + 4 + 3 + 21 = 100


Other ways of making number 100 (withiout using number 32)
98 + 7 + 6 - 5 - 4 - 3 + 2 - 1 = 100
98 - 7 - 6 - 5 - 4 + 3 + 21 = 100
9 - 8 + 76 - 5 + 4 + 3 + 21 = 100
98 - 7 + 6 + 5 + 4 - 3 - 2 - 1 = 100
98 + 7 - 6 + 5 - 4 + 3 - 2 - 1 = 100
98 + 7 - 6 + 5 - 4 - 3 + 2 + 1 = 100
98 - 7 + 6 + 5 - 4 + 3 - 2 + 1 = 100
98 - 7 + 6 - 5 + 4 + 3 + 2 - 1 = 100
98 + 7 - 6 - 5 + 4 + 3 - 2 + 1 = 100
98 - 7 - 6 + 5 + 4 + 3 + 2 + 1 = 100
9 + 8 + 76 + 5 + 4 - 3 + 2 - 1 = 100
9 + 8 + 76 + 5 - 4 + 3 + 2 + 1 = 100

Solution:

Sam : 2
Dean : 5
Castiel : 7

Age diff
7 - 2 = '5' is prime
7 - 5 = '2' is prime
5 - 2 = '3' is prime

Solution:

He should draw any chit of paper and before unfolding it, he must eat and swallow the chit. In this manner, to determine the judgment of the god, they will have to look at the other chit which will have 'Guilty' written over it. Thus everyone will believe that the chit which he ate had innocent written over it and thus they will believe that he is innocent.

Solution:

It can be done in 8 moves as shown in the animated image below.

Solution:

He should shoot at the ground.

If Kangwa shoots the ground, it is Rafael's turn. Rafael would rather shoot at Ferdinand than Kangwa, because he is better.
If Rafael kills Ferdinand, it is just Kangwa and Rafael left, giving Kangwa a fair chance of winning.
If Rafael does not kill Ferdinand, it is Ferdinand's turn. He would rather shoot at Rafael and will definitely kill him. Even though it is now Kangwa against Ferdinand, Kangwa has a better chance of winning than before.

Solution:

7

Explanation:
8th is bald man head, check the video below.

Solution:

All Digits [0-9] follow the following pattern: There is one occurrence of all digits in every 10 numbers Example. Digit-9 occurred one time between 10 and 19 in 9, between 20 and 29 in 29
However, for tens(91,92,93...99) and hundreds (900,901.... 999), the occurrence is much more. Since we have included 1000, Therefor 1 is the most occurred digit.
Note: Despite three '0s' in 1000, 0 is not most occurred digit as they don't have tens and hundreds like other digits.

Solution:

A) Fill 5 ml gallon ( 5mlGallon - 5, 3mlGallon - 0)
B) Transfer to 3 ml gallon (5mlGallon - 2, 3mlGallon - 3)
C) Empty 3 ml gallon ( 5mlGallon - 2, 3mlGallon - 0)
D) Transfer 2 ml from 5 ml gallon to 3 ml gallon (5mlGallon - 0, 3mlGallon - 2)
E) Fill 5 ml gallon(5mlGallon - 5, 3mlGallon - 2)
F) Transfer 1 ml from 5 ml gallon to 3 ml gallons(5mlGallon - 4, 3mlGallon - 3)

Solution:

The person on 73rd number will survive.

Explanation:
Till the number is the power of 2, the last person to survive will be the one who started it. But since the number here is not the power of 2, we will take the greatest power of 2 that is less than the number which is 64.
100 - 64 = 36
36 people are killed as 2, 4, 6, ..., 72. Thus the sword will now be given to the 73rd person. Now he is the first person to start in the remaining 64 people. Thus he will be the one to survive.