Solution:

Are you Thorgan

Explanation:
Below will be the reply of three brothers:
Eden: No (speaks truth)
Thorgan: No (speaks lie)
Kylian: Yes (speaks lie)

Therefore if its Kylian then only you will get a reply as "Yes" and then you ask for your money.

Solution:

13 numbers

Explanation:
Since we are looking to find odd reminder which implies that the remainder will be either 1 or 3
Therefore number must follow below two conditions:
A) We can list number 5n + 1 or 5n + 3. (where n = 0,1,2,3.....)
B) The number must end in 1 or 3.

List of such numbers less than 100 are:
1, 3, 11, 13, 21, 23, 31, 33, 41, 43, 51, 53, 61, 63, 71, 73, 81, 83, 91, 93

Let's remove the nonprime ones which are 1, 21, 33, 51, 63, 81 and 91

So, I will be left with 13 numbers which fit the bill.
3, 11, 13, 23, 31, 41, 43, 53, 61, 71, 73, 83 and 93

Solution:

We now have a square of 3x3 size, 2 squares of 2x2 size and 5 squares of 1x1 size.

Solution:

Old password : altered

New Password : distinct

Solution:

Sam : 2
Dean : 5
Castiel : 7

Age diff
7 - 2 = '5' is prime
7 - 5 = '2' is prime
5 - 2 = '3' is prime

Solution:

Yes, some people are going get really tiny pieces but you were allowed for that right. Also, there is another way of doing it. Can you think of it?

Solution:

The Stars

Solution:

David to play second

Explanation:
Let's suppose that David plays first and he picks 9. Then Albert will definitely pick 8. Now, David will have to pick 7 or Albert will pick 7 in his turn. But if David picks up 7, then he will score 16 that is beyond 15 and will lose. So one thing is for sure, no one will be willing to start with the highest digits.

Suppose David plays first and picks up 1, Albert will pick 2. Then David will pick 3 and Albert will pick 4. Now David will be forced to pick 9. The score is 6 to 13 and thus David will have no chance of winning.

If David Picks 9 after Albert has picked up 2, then Albert will pick 8 and the score will become 10 to 10. Thus David will pick 3 as picking 7 will send him past 15. Now Albert will pick 4 and David has nothing to pick for winning. Thus Albert wins.

Therefore, you should suggest David to play second.

Solution:

This can be done if you draw a five pointed star and place the balls on the corners and intersection points. See the figure to understand better.

Solution:

I spoke with Joe.

Explanation:
There can be only two cases. Either Zoe is a liar or Joe is a liar.

First Case
Let us assume that Zoe is a liar and Joe is a truthful person.
If I asked the question from Joe, the answer will be yes. If I asked the question from Zoe, the answer will be no. Thus in this case, I must have asked from Joe.

Second Case
Let us assume that Zoe is a truthful and Joe is a liar.
If I asked the question from Joe, the answer will be yes. If I asked the question from Zoe, the answer will be no. Thus in this case as well, I must have asked from Joe only.

Solution:

1. Fill 5 liters jar ( 5l-jar:5, 3l-jar:0)
2. Transfer to 3 liters pail (5l-jar:2, 3l-jar:3)
3. Empty 3 liters jar ( 5l-jar:2, 3l-jar:0)
4. Transfer 2q from 5 pail to 3 pail (5l-jar:0, 3l-jar:2)
5. Fill 5 liters pail(5l-jar:5, 3l-jar:2)
6. Transfer 1q from 5 pail to 3 pail(5l-jar:4, 3l-jar:3)